Block copolymer assembly to control fluid rheology

نویسندگان

  • S. R. Bhatia
  • A. Mourchid
  • M. Joanicot
چکیده

Recent experimental studies on the rheology of block copolymer micelles are reviewed. Where appropriate, we draw analogies between the viscoelastic properties of polymeric micelles and those of colloidal dispersions. We also present some important differences between these two classes of complex fluids, namely the ability to tune self-assembly through solvent polymer interactions. Finally, new experimental results for attractive micellar solutions of polyelectrolytes are presented. 2001 Elsevier Science Ltd. All rights reserved.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Coarse-grained molecular dynamics study of block copolymer/nanoparticle composites under elongational flow.

Symmetric diblock copolymer/nanoparticle (NP) systems under planar elongational flow have been modeled and simulated using coarse-grained nonequilibrium molecular dynamics. The aim of our present study is to understand how the dispersion of NPs in a block copolymer system is influenced by elongational flow and how the presence of NPs changes the rheology and flow-induced morphology transition i...

متن کامل

Block Copolymer Self Assembly for Design and Vapor Phase Synthesis of One-Dimensional Nanostructured Materials

Block copolymer thin films provide a robust method for generating regular, uniform patterns with sub-100 nanometer length scales over arbitrarily large areas. A significant advantage of such block copolymer-based patterning is its ease of integration with all other aspects of traditional thin-film processing, including plasma-based etching and metallization. Such process compatibility ensures a...

متن کامل

Coarse-grained molecular dynamics simulation on the placement of nanoparticles within symmetric diblock copolymers under shear flow.

We present molecular dynamics simulations coupled with a dissipative particle dynamics thermostat to model and simulate the behavior of symmetric diblock copolymer/nanoparticle systems under simple shear flow. We consider two categories of nanoparticles, one with selective interactions toward one of the blocks of a model diblock copolymer and the other with nonselective interactions with both b...

متن کامل

Hydrodynamic self-consistent field theory for inhomogeneous polymer melts.

We introduce a mesoscale technique for simulating the structure and rheology of block-copolymer melts and blends in hydrodynamic flows. The technique couples dynamic self-consistent field theory with continuum hydrodynamics and flow penalization to simulate polymeric fluid flows in channels of arbitrary geometry. We demonstrate the method by studying phase separation of an ABC triblock copolyme...

متن کامل

Study on Rheological Property Control Method of “Three High” Water Based Drilling Fluid

The rheological regulation of the “three high” (high temperature, high density and high salinity) water-based drilling fluid is a worldwide problem due to the combined influence of temperature, solid content and salinity. This paper investigates the factors and regulation methods about rheological property of “three high” water based drilling fluid, and the effects of clay, salinity and weighti...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2001